Revista: | Quimica nova |
Base de datos: | PERIÓDICA |
Número de sistema: | 000313275 |
ISSN: | 0100-4042 |
Autors: | Scotti, Rodrigo1 Lima, Eder C Benvenutti, Edilson V Piatnicki, Clarisse M.S Dias, Silvio L.P Gushikem, Yoshitaka2 Kubota, Lauro T |
Institucions: | 1Universidade Federal do Rio Grande do Sul, Instituto de Quimica, Porto Alegre, Rio Grande do Sul. Brasil 2Universidade Estadual de Campinas, Instituto de Quimica, Campinas, Sao Paulo. Brasil |
Any: | 2006 |
Període: | Abr |
Volum: | 29 |
Número: | 2 |
Paginació: | 208-212 |
País: | Brasil |
Idioma: | Portugués |
Tipo de documento: | Artículo |
Enfoque: | Experimental, aplicado |
Resumen en inglés | The electrochemical properties of methylene blue immobilized on cellulose/TiO2 and mixed oxide SiO2/TiO2 matrices were investigated by means of cyclic voltammetry. The electron mediator property of the methylene blue was optimized using a factorial design, consisting of four factors in two levels. The experimental observations and data analyses on the system indicate that the lowest peak separation occurs for Sil/TiOAM, 1.0 mol L-1 KCl solution and 20 mV s-1 scan rate, while values of current ratio closest to unity were found for Cel/TiOAM independent of electrolyte concentration, 0.2 or 1.0 mol L-1, and scan rate, 20 mV s-1 or 60 mV s-1 |
Disciplines | Química |
Paraules clau: | Electroquímica, Azul de metileno, Voltametría cíclica, Diseño factorial |
Keyword: | Chemistry, Electrochemistry, Methylene blue, Cyclic voltammetry, Factorial design |
Text complet: | Texto completo (Ver HTML) |