| Revista: | Materials research |
| Base de datos: | PERIÓDICA |
| Número de sistema: | 000312735 |
| ISSN: | 1516-1439 |
| Autors: | Cunha, Fernanda Oliveira Vieira da1 Melo, Diogo Henrique Roesler Veronese, Vinicius Bassanesi Forte, Maria Madalena Camargo |
| Institucions: | 1Universidade Federal do Rio Grande do Sul, Escola de Engenharia, Porto Alegre, Rio Grande do Sul. Brasil |
| Any: | 2004 |
| Període: | Oct-Dic |
| Volum: | 7 |
| Número: | 4 |
| Paginació: | 539-543 |
| País: | Brasil |
| Idioma: | Inglés |
| Tipo de documento: | Nota breve o noticia |
| Enfoque: | Experimental |
| Resumen en inglés | In this work was employed a 23 factorial experiment design to evaluate the castor oil polyurethane-poly(methyl methacrylate) semi-IPN synthesis. The reaction parameters used as independent variables were NCO/OH molar ratio, polyurethane polymerization time and methyl methacrylate (MMA) content. The semi-IPNs were cured over 28 h using two thermal treatments. The polymers were characterized by infrared and Raman spectroscopy, thermal analysis and swelling profiles in n-hexane. The glass transition temperature (Tg) and the swelling were more affect by the NCO/OH molar ratio variation. The semi-IPNs showed Tg from - 27 to - 6 °C and the swelling range was from 3 to 22%, according to the crosslink density. The IPN mechanical properties were dependent on the cure temperature and MMA content in it. Lower elastic modulus values were observed in IPNs cured at room temperature |
| Disciplines | Ingeniería, Química |
| Paraules clau: | Ingeniería de materiales, Química de polímeros, Química industrial, Aceite de ricino, Poliuretano, Propiedades mecánicas, Temperatura |
| Keyword: | Engineering, Chemistry, Materials engineering, Industrial chemistry, Polymer chemistry, Castor oil, Polyurethane, Mechanical properties, Temperature |
| Text complet: | Texto completo (Ver HTML) |
