The influence of temperature on the decomposition kinetics of peracetic acid in solutions



Título del documento: The influence of temperature on the decomposition kinetics of peracetic acid in solutions
Revista: Brazilian journal of chemical engineering
Base de datos: PERIÓDICA
Número de sistema: 000308794
ISSN: 0104-6632
Autors: 1




Institucions: 1Escola de Engenharia Maua, Departamento de Engenharia Quimica e de Alimentos, Sao Caetano do Sul, Sao Paulo. Brasil
Any:
Període: Jun
Volum: 18
Número: N
Paginació: 217-220
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, aplicado
Resumen en inglés Peracetic acid is a powerful sanitizer that has only recently been introduced in the Brazilian food industry. The main disadvantage of this sanitizer is its decomposition rate. The main purpose of this paper is to present results obtained in experiments carried out to study the decomposition kinetics of peracetic acid in aqueous solutions at 25, 35, 40 and 45 °C. The decompositon of peracetic acid is a first-order reaction. The decomposition rate constants are between 1.71x10-3 h -1 for 25 °C and 9.64x10-3 h-1 for 45 °C. The decomposition rate constant is affected by temperature according to the Arrhenius equation, and the activation energy for the decomposition of peracetic acid in aqueous solutions prepared from the commercial formulation used in this work is 66.20 kJ/mol
Disciplines Química
Paraules clau: Química de alimentos,
Ingeniería química,
Sanitizantes,
Acido peracético,
Cinética de degradación,
Efectos de la temperatura,
pH
Keyword: Chemistry,
Food chemistry,
Chemical engineering,
Sanitizers,
Peracetic acid,
Decomposition kinetics,
Temperature effects,
pH
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