Group contribution lattice fluid equation of state: application to polymer+solvent systems



Título del documento: Group contribution lattice fluid equation of state: application to polymer+solvent systems
Revista: Brazilian journal of chemical engineering
Base de datos: PERIÓDICA
Número de sistema: 000308604
ISSN: 0104-6632
Autors: 1

Institucions: 1Universidade Federal do Rio de Janeiro, Escola de Quimica, Rio de Janeiro. Brasil
Any:
Període: Sep
Volum: 15
Número: 3
Paginació: 313-319
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, analítico
Resumen en inglés A group contribution equation of state recently proposed by the authors is used to calculate the activity of solvents in polymer+solvent solutions. The model is based on the generalized van der Waals theory and combines the Staverman-Guggenheim combinatorial term with an attractive lattice gas expression. The results show that the equation correlates the properties of pure solvents and polymers accurately. Furthermore, the equation satisfactorily represents the vapor-liquid equilibrium of solutions containing polymer and solvents of different polarities
Disciplines Química
Paraules clau: Química de polímeros,
Solventes,
Ecuaciones de estado
Keyword: Chemistry,
Polymer chemistry,
Solvents,
Equations of state
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