| Revista: | Brazilian journal of chemical engineering |
| Base de datos: | PERIÓDICA |
| Número de sistema: | 000308946 |
| ISSN: | 0104-6632 |
| Autors: | Freire, F.B1 McKenna, T.F2 Othman, S Giudici, R |
| Institucions: | 1Universidade de Sao Paulo, Escola Politecnica, Sao Paulo. Brasil 2Universite Claude Bernard Lyon 1, Villeurbanne, Rhone-Alpes. Francia |
| Any: | 2004 |
| Període: | Jun |
| Volum: | 21 |
| Número: | 2 |
| Paginació: | 293-305 |
| País: | Brasil |
| Idioma: | Inglés |
| Tipo de documento: | Artículo |
| Enfoque: | Experimental, aplicado |
| Resumen en inglés | This work is concerned with the coupled estimation of the heat generated by the reaction (Qr) and the overall heat transfer parameter (UA) during the terpolymerization of styrene, butyl acrylate and methyl methacrylate from temperature measurements and the reactor heat balance. By making specific assumptions about the dynamics of the evolution of UA and Q R, we propose a cascade of observers to successively estimate these two parameters without the need for additional measurements of on-line samples. One further aspect of our approach is that only the energy balance around the reactor was employed. It means that the flow rate of the cooling jacket fluid was not required |
| Disciplines | Química |
| Paraules clau: | Química de polímeros, Polimerización por emulsión, Calorimetría indirecta, Intercambio de calor, Estimación de estado |
| Keyword: | Chemistry, Polymer chemistry, Emulsion polymerization, Indirect calorimetry, Heat exchange, State estimation |
| Text complet: | Texto completo (Ver HTML) |
