A Dual-mode model interpretation of CO2/CH4 permeability in polysulfone membranes at low pressures



Título del documento: A Dual-mode model interpretation of CO2/CH4 permeability in polysulfone membranes at low pressures
Revista: Anais da Academia Brasileira de Ciencias
Base de datos: PERIÓDICA
Número de sistema: 000420312
ISSN: 0001-3765
Autors: 1
1
1
1
Institucions: 1Caxias do Sul University, Exact Sciences Center and Technologies, Caxias do Sul, Rio Grande do Sul. Brasil
Any:
Període: Jun
Volum: 90
Número: 2
Paginació: 1855-1864
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico
Resumen en inglés An asymmetric membrane of polysulfone (PSf) was synthesized by phase inversion method. Permeation experiments were carried out between 2 to 5 bar pressure, and at temperatures 20 to 45°C. The dense- selective layer of PSf membrane presents regular thickness (about 5 μm), and was not possible to observe the formation of macrovoids in porous layer. The CO 2 permeability through membrane was 18.8 Barrer at 35°C and 2 bar pressure, and this relationship between the pressure and the CO 2 permeability was described adequately by Dual-mode model. The absence of CH 4 permeability at 2 and 3 bar pressure, qualifies the PSf membrane for gases separation with high selectivity in this range
Disciplines Química,
Ingeniería
Paraules clau: Química de polímeros,
Ingeniería química,
Membranas asimétricas,
Permeabilidad CO2 /CH4,
Modelo de modo dual,
Polisulfonas
Keyword: Polymer chemistry,
Chemical engineering,
Asymmetric membranes,
CO2/CH4 permeability,
Dual-mode model,
Polysulfone
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